First of all make sure to install on the new system, the same version of Servers Alive as on the old system.
Then you can create a backup of the setup settings (this includes people/team/protocols too) by doing:
* start regedit and goto HKEY_LOCAL_MACHINESOFTWAREDBU ConsultingServers Alive
* select EXPORT registry from the REGISTRY (or FILE) menu.
* copy the created .REG file to the new system
* execute the .REG file (double click on it) on the new system (this will insert the setup info into the registry of the new system)
* copy the entriesfile, groups.grp file and all eventual templates to the new system